Rapid Interception of Cn F2n+1 (O)SO. Radical with Copper-Based Carbene: A Novel Access to Perfluoroalkanesulfinate Ester
Wang, Hanghang;Li, Haiyan;Zheng, Yonggao;Lian, Pengcheng;Wan, Xiaobing*（万小兵）
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou, Jiangsu, 215123, P. R. China.
Chemistry (Weinheim an der Bergstrasse, Germany),2019,25(9), 2195--2198
In this communication, an unprecedented interception of Cn F2n+1 (O)SO. radical with a copper-based carbene has been established. Distinguished by wide substrate scopes and mild reaction conditions, this novel radical-carbene coupling reaction (RCC reaction) provides a fundamentally different and mechanistically interesting strategy for the synthesis of perfluoroalkanesulfinate esters.
链接：https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201800718
欢迎进入,苏州大学材料与化学化工学部 苏州大学 English 切换导航 ...Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road...RapidInterceptionofCnF2n+1(O)SO.RadicalwithCopper-BasedCarbene:ANovelAccesstoPerfluoroalkanesulfinateEsterWang,Hanghang;Li,Haiyan;Zheng,Yonggao;Lian,Pengcheng;Wan,Xiaobing*（万小兵）KeyLaboratoryofOrganicSynthesisofJiangsuProvince,CollegeofChemistry,ChemicalEngineeringandMaterialsScience,SoochowUniversity,199Ren-AiRoad,Suzhou,Jiangsu,215123,P.R.China.Chemistry(WeinheimanderBergstrasse,Germany),2019,25(9),2195--2198Inthiscommunication,anunprecedentedinterceptionofCnF2n+1(O)SO.radicalwithacopper-basedc万小兵教授在 Chemistry (Weinheim an der Bergstrasse, Germany) 上发表研究论文
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